作者单位
摘要
北京工业大学材料与制造学部激光工程研究院,北京 100124
表面增强拉曼光谱(SERS)是一种高灵敏的分子振动指纹光谱技术。光辅助化学还原制备SERS衬底具有成本低、环境适用性强等优势,但在微纳结构多样化制造方面存在局限性,限制了SERS衬底的检出性能。笔者系统研究了介质微球独特的聚焦特性,揭示了微球直径对聚焦光场分布的调控规律,在微球底部实现了可控的光场空间分布,实现了多级银微纳结构的快速光还原合成。进一步,通过优化制备参数(前驱液浓度比、激光辐照功率及辐照时间),成功制备了具有优异拉曼增强效果的多级银纳米颗粒/银微环/介质微球(AgNPs/AgMRs/MS)复合结构。通过介质微球和多级银微纳结构(AgNPs/AgMRs)中的光场耦合,即微球聚焦、多级银微纳结构局域表面等离激元共振以及复合结构定向发射等,实现了10-14 mol/L的痕量检测,增强因子可达9.50×109,为光化学还原制备高性能介质-金属复合SERS衬底提供了新思路。
光谱学 表面增强拉曼光谱 多级银微纳结构 光化学还原 介质微球 
中国激光
2024, 51(4): 0402404
作者单位
摘要
河南理工大学 物理与电子信息学院,焦作 454000
为解决低光照环境下机器视觉采集图像存在的对比度低、细节丢失等问题,提出了一种基于扩展大气散射模型的低光照图像增强算法。首先,将低光照图像三个颜色通道的最大值作为初始传输图,并使用伽马校正调整图像的可见性和边缘细节;接着,利用融合技术优化初始传输图,融合不同方法提取的主要结构和精细结构;然后,利用亮通道的暗像素计算逆大气光值;最后,根据传输图和逆大气光值对模型进行求解得到最终增强图像。模型中的校正项可以更好地抑制增强图像的过度增强与细节丢失,同时,算法采用图像融合对传输图进行优化,可以较好地再现图像中的轮廓和纹理细节。实验结果表明,相比于其他8种算法,该算法在提高图像对比度、自然度和突出细节方面表现出了更好的性能。
图像处理 图像增强 大气散射模型 图像融合 传输图 亮通道 大气光值 Image processing Image enhancement Atmospheric scattering model Image fusion Transmission map Bright channel Atmospheric light value 
光子学报
2023, 52(6): 0610002
Bingbing Chen 1,2,3,4Pengyang Wang 1,2,3,4Ningyu Ren 1,2,3,4,5Renjie Li 1,2,3,4[ ... ]Xiaodan Zhang 1,2,3,4
Author Affiliations
Abstract
1 Institute of Photoelectronic Thin Film Devices and Technology, Renewable Energy Conversion and Storage Center, Solar Energy Conversion Center, Nankai University, Tianjin 300350, China
2 Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Tianjin 300350, China
3 Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education, Tianjin 300350, China
4 Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China
5 School of Physical Science and Technology, Inner Mongolia University, Key Laboratory of Semiconductor, Hohhot 010021, China
Inverted perovskite solar cells (IPSCs) have attracted tremendous research interest in recent years due to their applications in perovskite/silicon tandem solar cells. However, further performance improvements and long-term stability issues are the main obstacles that deeply hinder the development of devices. Herein, we demonstrate a facile atomic layer deposition (ALD) processed tin dioxide (SnO2) as an additional buffer layer for efficient and stable wide-bandgap IPSCs. The additional buffer layer increases the shunt resistance and reduces the reverse current saturation density, resulting in the enhancement of efficiency from 19.23% to 21.13%. The target device with a bandgap of 1.63 eV obtains open-circuit voltage of 1.19 V, short circuit current density of 21.86 mA/cm2, and fill factor of 81.07%. More importantly, the compact and stable SnO2 film invests the IPSCs with superhydrophobicity, thus significantly enhancing the moisture resistance. Eventually, the target device can maintain 90% of its initial efficiency after 600 h storage in ambient conditions with relative humidity of 20%–40% without encapsulation. The ALD-processed SnO2 provides a promising way to boost the efficiency and stability of IPSCs, and a great potential for perovskite-based tandem solar cells in the near future.
Journal of Semiconductors
2022, 43(5): 052201
Jie Zhang 1,2,3,4Shixin Hou 1,2,3,4Renjie Li 1,2,3,4Bingbing Chen 1,2,3,4[ ... ]Xiaodan Zhang 1,2,3,4
Author Affiliations
Abstract
1 Institute of Photoelectronic Thin Film Devices and Technology of Nankai University, Tianjin 300350, China
2 Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Tianjin 300350, China
3 Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China
4 Renewable Energy Conversion and Storage Center of Nankai University, Tianjin 300072, China
Interface engineering has played an increasingly essential role in the development of perovskite solar cells (PSCs). Herein, we adopted an effective and simple one-step interface passivation method on a FA-based perovskite to fabricate efficient and stable planar PSCs. The surface defects are reduced by the perovskite interface passivation layer incorporated between the hole transport and perovskite absorber layers, and then non-radiative recombination is suppressed while interfacial carrier extraction is enhanced. The passivated planar PSCs demonstrates 20.83% power conversion efficiency (PCE), which is caused by the simultaneous enhancement of the fill factor and open-circuit voltage. In addition, the device also shows great ambient and thermal stability. It retains 94% of its original PCE after 1000 h under ambient air without encapsulation as well as 90% of its initial efficiency after 400 h under continuous heating at 65 °C with encapsulation. This research provides a strategy for the development of efficient and stable PSCs.
Journal of Semiconductors
2020, 41(5): 052202
作者单位
摘要
1 上海师范大学 化学与材料科学学院, 上海 200234
2 中国科学院 上海硅酸盐研究所, 中国科学院特种无机涂层重点实验室, 上海 201899
化学气相沉积法是制备大尺寸、高质量石墨烯的有效方法, 其中金属催化剂的性能直接关系到所制备的石墨烯材料的品质, 因此需对金属催化剂进行表面预处理。本文研究了不同的预处理工艺对常用的铜基底催化剂表面状态的影响, 提出了钝化膏酸洗和电化学抛光协同处理的有效方法, 并对电化学抛光工艺参数(抛光电压、时间)以及铜基底退火工艺(退火温度、时间)等进行了系统研究。研究表明: 电化学抛光电压过高、抛光时间过长容易导致过度抛光, 合适的抛光电压和抛光时间分别为8 V和8 min。退火温度和时间对铜催化剂表面晶粒形态影响较大, 经1000 ℃退火处理30 min后, 铜箔表面晶粒尺寸更大, 分布更均匀。此外, 对CVD法生长制备的石墨烯样品进行表征, 电镜图片和拉曼光谱显示, 获得的石墨烯薄膜的层数较少, 且结构缺陷较少。
铜基底 预处理 化学气相沉积法 石墨烯 copper substrate pretreatment chemical vapor deposition graphene 
无机材料学报
2020, 35(10): 1177
作者单位
摘要
1 安徽大学电气工程与自动化学院, 安徽 合肥 230601
2 安徽大学教育部电能质量工程研究中心, 安徽 合肥 230601
3 合肥师范学院电子信息系统仿真设计安徽省重点实验室, 安徽 合肥 230601
针对太阳能电池片微弱缺陷难以检测的特点,提出一种基于小波域信号突变点捕捉的缺陷检测法。该方法基于一维离散信号,在小波域逐列对图像进行突变点检测,实现了对信号突变点的捕捉,并采用能量重心法对其进行校正,获得了缺陷图像所对应的正常背景,最后对原图像与恢复后的背景图像作简单的代数融合,以凸显缺陷区域。实验表明,该方法对太阳能电池片的多种表面缺陷检测具有有效性。
图像处理 缺陷检测 小波分解 能量重心法 信号突变点 
激光与光电子学进展
2020, 57(6): 061101
作者单位
摘要
Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan, 430074, China
The work function (WF) of indium-tin-oxide (ITO) substrates plays an important role on the inverted organic photovoltaic device performance. And electrode engineering has been a useful method to facilitate carrier extraction or charge collection to enhance organic photovoltaic (OPV) performance. By using self-assembly technique, we have deposited poly(dimethyl diallylammonium chloride) (PDDA) layers onto ITO coated glass substrates. The results indicate that the surface WF of ITO is reduced by about 0.3 eV after PDDA modification, which is attributed to the modulation in electron affinity. In addition, the surface roughness of ITO substrate became smaller after PDDA modification. These modified ITO substrates can be applied to fabricate inverted OPVs, in which ITO works as the cathode to collect electrons. As a result, the photovoltaic performance of inverted OPV is substantially improved, mainly reflecting on the increase of short circuit current density.
organic photovoltaic (OPV) organic photovoltaic (OPV) indium tin oxide (ITO) indium tin oxide (ITO) inverted structure inverted structure surface modification surface modification work function (WF) work function (WF) 
Frontiers of Optoelectronics
2015, 8(3): 269

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